Publications internationales

2015
(2015), Enantioselective Deacetylation of Some Benzylic Acetate Derivatives Via Alcoholysis in Non-aqueous M : Springer, http://link.springer.com/article/10.1007/s10562-014-1470-7

Résumé: Enantioselective deacetylation of a set of benzylic acetates via alcoholysis catalyzed by Lipase B from Candida antarctica (CAL-B), under mild conditions is described. A systematic study allows to determine the appropriate combination nucleophile/organic solvent and also to explain the influence of these parameters on the enzymatic catalytic reaction. In all cases, (R)-alcohols are obtained with high ee (up to >99 %) at conversion 36 % < C < 48 %, the selectivity reaching E > 500. The enzymatic reactivity is influenced by the hydrophobicity of solvent and the structure/nature of the nucleophile. Furthermore, CAL-B allows enantio-complementary between transesterifications in non-aqueous media: alcoholysis and acetylation.

2012
(2012), Green methodology for enzymatic hydrolysis of acetates in non-aqueous media via carbonate salts. Tetrahedron: Asymmetry, 23, 2012, 828-833. : Elsevier, http://www.sciencedirect.com/science/article/pii/S0957416612002960
(2012), Insight into the stereoselectivity of PPL-catalyzed formation of polyesters from phenyl glycidyl eth. European Polymer Journal, Vol33, Issue 46, 2012, 6967-6970. : Elsevier, http://www.sciencedirect.com/science/article/pii/S0014305712001206